The carbon-silicon bond in alkenyl(alkoxy)silanes is readily cleaved by hydrogen peroxide to form the corresponding aldehydes, carboxylic acids or ketones, depending upon the nature of the alkenyl group and the reaction conditions. We have recently reported that the silicon-carbon bond in alkyl(alk
✦ LIBER ✦
Silafunctional compounds in organic synthesis. 29.1 Oxidation of (alkenyl)alkoxysilanes to α-hydroxy ketones
✍ Scribed by Kohei Tamao; Kimio Maeda
- Book ID
- 104218055
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 230 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Silafunctional compounds in organic synt
✍
Kohei Tamao; Makoto Kumada; Kimio Maeda
📂
Article
📅
1984
🏛
Elsevier Science
🌐
French
⚖ 232 KB
Silafunctional compounds in organic synt
✍
Kohei Tamao; Tetsu Tanaka; Takashi Nakajima; Ritsuo Sumiya; Hitoshi Arai; Yoshih
📂
Article
📅
1986
🏛
Elsevier Science
🌐
French
⚖ 257 KB
Intramolecular hydrosilation of ally1 and homoallyl alcohols and the subsequent oxidative cleavage of the resultant carbon-silicon bond have provided a new approach to the regio-controlled synthesis of 1,2-and/or 1,3-diols. We have recently developed a new methodology for the anti-Markownikoff hydra
Silafunctional compounds in organic synt
✍
Kohei Tamao; Neyoshi Ishida
📂
Article
📅
1984
🏛
Elsevier Science
🌐
French
⚖ 193 KB