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Silaethylene intermediates from .alpha.-lithiosilanes. 2. Reactions with chlorosilanes and 1,3-butadiene

โœ Scribed by Jones, Paul Ronald; Lim, Thomas F. O.


Book ID
126110446
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
663 KB
Volume
99
Category
Article
ISSN
0002-7863

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1,3-Disubstituted triazenes 3 are oxidized with ten-butyl hypochlorite to N-chlorotriazenes 4, which at low temperatures with antimony pentachloride afford 1,3-diaza-2-azoniaallene salts 5 as reactive intermediates. Cations 5 undergo cycloadditions to one or both double bonds of 1,3-butadienes to fu