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Silacyclopropene-to-vinylsilylene isomerization in reactions of silyl- and hydridosilylenes with acetylenes

โœ Scribed by Barton, Thomas J.; Burns, Stephanie A.; Burns, Gary T.


Book ID
126187376
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
213 KB
Volume
2
Category
Article
ISSN
0276-7333

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Isomerization of linear C3H3+in its reac
โœ Mehdi Moini ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 562 KB

The isomerization of linear C3H 3 (+) in its reaction with acetylene to cyclic C3H 3 (+) was studied with a quadrupole ion trap mass spectrometer. The reaction of linear C3H 3 (+) with (13)C2H2 shows that isomerization takes place via a [C5H 5 (+) ](\*) activated complex that is unstable relative to