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Silacyclobutenes: Synthesis and Reactivity

✍ Scribed by Javad Mohseni-Ala; Norbert Auner

Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Facile Synthesis of Si-Functional Silacy
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Combination of 1,2-hydroboration and 1,1
Combination of 1,2-hydroboration and 1,1-organoboration: synthesis of novel organo-substituted 1-silacyclobutenes
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## Abstract The reaction of di(alkyn‐1‐yl)silanes Me(R)Si(Cο£½C^__t__^Bu)~2~ [1; R = Me (a), H (b)] with diethylborane or 9‐borabicyclo[3.3.1]nonane in a 1 : 1 ratio affords the 1‐silacyclobutene derivatives 6a, 7a,b as a result of intermolecular 1,1‐hydroboration followed by intramolecular 1,1‐organ