𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Significance of the Geminal Dimethyl Group in the Odor Principle of Ambrox®

✍ Scribed by Günther Ohloff; Wolfgang Giersch; Wilhelm Pickenhagen; Anton Furrer; Beatrice Frei

Book ID
102255136
Publisher
John Wiley and Sons
Year
1985
Tongue
German
Weight
388 KB
Volume
68
Category
Article
ISSN
0018-019X

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✦ Synopsis

Ambro,z@ is a registered trade name of Firmenich SA. Systematic name of ambrox: [3a R-(3aa,5~~.9aa,9b~)/dodecuhydro-3a,6,6,9a-tetramethylnaphtho[2, Iblfuran.

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On the interaction of geminal fluorines
On the interaction of geminal fluorines and geminal cyano groups. ‘anomalous’ ordering of rotational barriers in fluoroethanes
✍ Leo Radom; Peter J. Stiles 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 226 KB

In the course of a study of an additivity scheme for conformational energies of substituted ethanes, 2,3 we were intrigued by the lack of additivity displayed by the haloethanes. Thus, whereas monofluoro-substitution in ethane leads to an increase in experimentally observed barrier from 2.93 to 3.33