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Significance of 4-Phenyl-1,2,4-triazoline-3,5-dione (PTAD) in the GC–MS Identification of Conjugated Fatty Acid Positional Isomers

✍ Scribed by Utkarsh Shah, Jackson O. Lay Jr., Andrew Proctor


Book ID
118817712
Publisher
Springer-Verlag
Year
2012
Tongue
English
Weight
256 KB
Volume
90
Category
Article
ISSN
0003-021X

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Cycloaddition of PTAD to 7-methylenenorbornene (1 a) afforded the rearrangement urazole 2a, but not with 7-(pheny1methylene)norbornene (1 b) and 7-(chloromethylene)norbornene (lc). Instead, besides the [2 + 23 cycloadducts 3b and 3c, respectively, l b gave the double [4 + 23 adduct 4b and l c the no