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Sign of the electric field gradient tensor and the nature of the low temperature phase transition in Fe(pyridine)2Cl2

✍ Scribed by W.M. Reiff; R.B. Frankel; B.F. Little; Gary J. Long

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 516 KB
Volume: 28
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)80018-7

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✦ Synopsis

Massbauer spectra of Fe(pyridine)gClz have been determined in large external magnetic fields at room temperatube and 78 K. The principal component OF the electric field >adient tensor is positive and consistent with nn electron .,

.in the d+ drbital. The results.indicate no change in orbital ground state for the low tempctature phase transition of this material.

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