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Sign and magnitude of the phosphorus–phosphorus coupling constant in the [cyclopentadienyltris(trimethylphosphine)iron]+ cation of [(η5-C5H5)(Me3P)3Fe]BF4and the 13C/12C isotope effect on the 31P chemical shift

✍ Scribed by Wolfgang Buchner; Wolfgang Ries; Wolfgang Malisch


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
184 KB
Volume
28
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The ^13^C NMR methyl group multiplet of the [cyclopentadienyltris(trimethylphosphine)iron]^+^ cation was simulated to obtain the sign and magnitude of the phosphorus‐phosphorus coupling constant and the ^13^C/^12^C isotope effect on the ^31^P chemical shift.