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Sigmatropic shifts with polyflouroaromatic compounds

✍ Scribed by G.M. Brooke; J.R. Cooperwaite; J.A.K.J. Ferguson; A.G. Morpeth


Book ID
104150078
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
45 KB
Volume
29
Category
Article
ISSN
0022-1139

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1,3-Sigmatropic Shifts in Carbonylketene
✍ Minh Tho Nguyen; Luc Landuyt; Hue Minh Thi Nguyen πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 124 KB

Antarafacial 1,3-sigmatropic shifts in carbonyl derivatives of PH 2 ΟΎ F ΟΎ OCH 3 ΟΎ OH ΟΎ SiH 3 ΟΎ H ΟΎ C 6 H 5 ΟΎ CH 3 . The barrier heights range from 10 kcal/mol for Cl migration to 35 ketenes, isocyanates, thioketenes and thioisocyanates have been studied by means of ab initio MO calculations. Energy