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Sigmatropic Rearrangement of Ammonium Ylides—Key Step in the Synthesis of Methyl 2-Formylphenyl Acetate

✍ Scribed by Kowalkowska, Anna; Jończyk, Andrzej


Book ID
111903122
Publisher
Taylor and Francis Group
Year
2011
Tongue
English
Weight
293 KB
Volume
41
Category
Article
ISSN
0039-7911

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New variously substituted 1-dimethylamino or 1-methylthio but-3-enylidene-bis-phosphonates have been prepared from readily available ␣-dimethylamino or ␣-methylthio methylene-bis-phosphonates by postulated [2,3]-Wittig rearrangements of the corresponding N-or S-allylic intermediate ylides.