.sigma.-Bond metathesis reactions of silicon-hydrogen and metal-silicon bonds. New routes to d0 metal silyl complexes

.sigma.-Bond metathesis reactions of sil

.sigma.-Bond metathesis reactions of silicon-hydrogen and metal-silicon bonds. New routes to d0 metal silyl complexes [Erratum to document cited in CA110(25):231799y]

✍ Woo, Hee Gweon; Tilley, T. Don 📂 Article 📅 1990 🏛 American Chemical Society 🌐 English ⚖ 127 KB

Versatile Conversion of N-Heterocyclic S

Versatile Conversion of N-Heterocyclic Silylene to Silyl Metal Compounds by Insertion of Divalent Silicon into Metal–Carbon and Metal–Hydrogen Bonds

✍ Dr. Yun Xiong; Dr. Shenglai Yao; Prof. Dr. Matthias Driess 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 270 KB

The facile one-pot reaction of the stable N-heterocyclic silylene LSi: 1 (L=(ArN)C(=CH(2))CH=C(Me)(NAr), Ar=2,6-iPr(2)C(6)H(3)) with Me(2)Zn, Me(3)Al, H(3)Al-NMe(3), and MeLi has been investigated. The silicon(II) atom in 1 is capable of insertion into the corresponding M-C and Al-H bonds under very

A new and general synthesis of .alpha.-s

A new and general synthesis of .alpha.-silyl carbonyl compounds by silicon-hydrogen insertion from transition metal-catalyzed reactions of diazo esters and diazo ketones

✍ Bagheri, Vahid; Doyle, Michael P.; Taunton, Jack; Claxton, E. Elizabeth 📂 Article 📅 1988 🏛 American Chemical Society 🌐 English ⚖ 396 KB

Catalytic Cross-Coupling Reaction of Est

Catalytic Cross-Coupling Reaction of Esters with Organoboron Compounds and Decarbonylative Reduction of Esters with HCOONH4: A New Route to Acyl Transition Metal Complexes Through the Cleavage of Acyl—-Oxygen Bonds in Esters.

✍ Hiroto Tatamidani; Kazuhiko Yokota; Fumitoshi Kakiuchi; Naoto Chatani 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

Catalytic Cross-Coupling Reaction of Est

Catalytic Cross-Coupling Reaction of Esters with Organoboron Compounds and Decarbonylative Reduction of Esters with HCOONH4: A New Route to Acyl Transition Metal Complexes Through the Cleavage of Acyl—-Oxygen Bonds in Esters.

✍ Hiroto Tatamidani; Kazuhiko Yokota; Fumitoshi Kakiuchi; Naoto Chatani 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

Catalytic Cross-Coupling Reaction of Est

Catalytic Cross-Coupling Reaction of Esters with Organoboron Compounds and Decarbonylative Reduction of Esters with HCOONH 4 : A New Route to Acyl Transition Metal Complexes through the Cleavage of Acyl−Oxygen Bonds in Esters

✍ Tatamidani, Hiroto; Yokota, Kazuhiko; Kakiuchi, Fumitoshi; Chatani, Naoto 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 368 KB