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Sigma Bond Activation by Cooperative Interaction with n s 2 Atoms: B + + n H 2

✍ Scribed by Sharp, Stephanie B.; Gellene, Gregory I.

Book ID
126915961
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
196 KB
Volume
120
Category
Article
ISSN
0002-7863

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## Abstract Ammonia borane (AB, NH~3~Β·BH~3~) was activated selectively __on the boron hydrogen atoms__ by [Ir(dppm)~2~]OTf, as shown by variable‐temperature ^31^P, ^11^B and ^1^H NMR studies, to yield __cis__‐ and __trans__‐[Ir(H)~2~(dppm)~2~]OTf dihydrides. X‐ray crystal structures of these comple