✦ LIBER ✦

Side reactions in macroscale electrolysis of halobenzenes in DMF at a mercury cathode

✍ Scribed by Juan Casado; Iluminada Gallardo

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 247 KB
Volume: 32
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(87)80025-7

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✦ Synopsis

Macroscale electrolysis of iodobenzene and bromobenzene at constant potential are reported. The number of electrons/molecule and the products obtained point out the participation of DMF, the supporting electrolyte and mercury cathode as reactants, and suggest the involvement of radical intermediates. Reaction pathways are proposed.

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