## Abstract A set of four hexapeptide sequences, each characterized by four strongly helicogenic Aib residues and all combinations of two isomeric Ile/__a__Ile residues at positions 2 and 5, was synthesized by solution methods and fully characterized. A detailed solution (by FTβIR absorption, NMR,
β¦ LIBER β¦
Side-Chain Chiral Centers of Amino Acid and Helical-Screw Handedness of Its Peptides
β Scribed by Tanaka, Masakazu; Anan, Kosuke; Demizu, Yosuke; Kurihara, Masaaki; Doi, Mitsunobu; Suemune, Hiroshi
- Book ID
- 118229635
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 103 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0002-7863
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**A tidal vortex (helix)** is formed, both rightβ and leftβhanded, where a violent tidal current meets a peaceful sea (the picture from Naruto City Tourist Association shows an example at Naruto channel, Japan). In contrast, Ξ±βhelices of proteins almost always show a rightβhanded helical screw sense