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Si60, an Analogue of C60?

โœ Scribed by Dr. Christian Zybill


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
326 KB
Volume
31
Category
Article
ISSN
0044-8249

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Si60, ein Analogon zu C60?
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Fullerene (C60) adsorption on Si surface
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Electronic structures of the icosahedral C&H,,, hydrocarbon and its perfhroro analog, C6nF6,,, are examined at the HF/4-31G and HF/6-3 lG\*\* levels. The calculated C-C bond lengths are as large as 1.57 A in C63Hb0 and 1.63 A in CbDF60. The bond lengthening is attributed to the H-H and F-F steric in

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Photo-transformation of G, C,,,, C,O, and C,Os in toluene results in destruction of these species. CW and CT0 are transformed with equal rates to form C,O and C,OO. No higher oxides of these fullerenes are formed. C,O is destroyed twice as fast and &,,02 approximately 40-50 times faster than Cs Prod