## Abstract The thermal decomposition of gaseous monomethylhydrazine (MMH) was studied by recording MMH absorption at 220 nm of the reacting gas behind a reflected shock wave at temperatures of 900โ1370 K, pressures of 140โ450 kPa, and in mixtures containing 97.5โ99 mol% argon. Based on previous wo
Shock-tube study of thermal decomposition of nitric oxide between 2700 and 3500 K
โ Scribed by Mitsuo Koshi; Tetsuro Asaba
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 467 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0538-8066
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โฆ Synopsis
Abstract
The decomposition of nitric oxide at temperatures ranging from 2700 to 3500 K was studied by means of the shock tube. The experimental data were reduced by the method described in a preceding paper and explained consistently by a set of the elementary reactions. The rate constant of the initiation reaction 2NO โ N~2~O + O, which was not well known in this temperature range, was deduced precisely. k~1~ was one order of magnitude lower than that reported previously in similar shockโtube experiments, and was consistent with results obtained below 2000 K and from the reverse reaction.
๐ SIMILAR VOLUMES
CH 3 NH 2 thermal decomposition is shown to provide a suitable NH 2 radical source for spectroscopic and kinetic shock tube studies. Using this precursor, the absorption coefficient of the NH 2 radical at a detection wavelength of 16739.90 cm ฯช1 has been determined. In the temperature range 1600-200