✦ LIBER ✦

Shock tube study of OH reactions with linear hydrocarbons near 1100 K

✍ Scribed by J. Brooke Koffend; N. Cohen

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 581 KB
Volume: 28
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1996)28:2<79::aid-kin2>3.0.co;2-i

No coin nor oath required. For personal study only.

✦ Synopsis

Reactions of the hydroxyl radical with several linear hydrocarbon species occurring in combustion chemistry have been considered at temperatures near I100 K and 1 atmosphere in shock tube experiments The OH density was monitored using 310 nm UV absorption of the A 'E+ -X 'n transition Rate coefficients for the reaction of OH with ethane (8.37 X c m ' molecule-' s -' , 970 K ) , hexane (2.18 X lo-", 962 K ) , heptane (3.34 X lo-", I186 K ) , octane (4.42 X lo-". 1078 K]. nonane (4.55 X lo-". 1097 K). and decane (5.64 X lo-". I 109 K) have been determined. These values are compared with previous experimental results and transition state theory calculations 0 1996 John Wiley G Sons. tnc

📜 SIMILAR VOLUMES

A shock tube study of reactions of CN wi

A shock tube study of reactions of CN with HCN, OH, and H2 using CN and OH laser absorption

✍ Steven T. Wooldridge; Ronald K. Hanson; Craig T. Bowman 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 979 KB

Quantitative, narrow-line laser absorption measurements of CN time-histories at 388 444 n m were acquired in high-temperature pyrolysis and laser photolysis shock tube experiments The data were analyzed using a detailed kinetics mechanism to determine the rate coefficients of the reactions C N + OH

High-temperature shock tube study of the

High-temperature shock tube study of the reactions CH3 + OH → products and CH3OH + Ar → products

✍ Venkatesh Vasudevan; Robert D. Cook; Ronald K. Hanson; Craig T. Bowman; David M. 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 251 KB 👁 1 views

## Abstract The reaction between methyl and hydroxyl radicals has been studied in reflected shock wave experiments using narrow‐linewidth OH laser absorption. OH radicals were generated by the rapid thermal decomposition of tert‐butyl hydroperoxide. Two different species were used as CH~3~ radical