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Ship-in-a-bottle formation of Pd13(CO)xclusters in zeolite NaY

✍ Scribed by L. L. Sheu; H. Knözinger; W. M. H. Sachtler

Book ID
112406581
Publisher
Springer US
Year
1989
Tongue
English
Weight
513 KB
Volume
2
Category
Article
ISSN
1011-372X

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Ship-in-bottle synthesis of palladium ca
Ship-in-bottle synthesis of palladium carbonyl complexes in NaY and NaX zeolites via the direct carbonylation of Pd(NH3)2+4
✍ Lucie Drozdová; Jana Nováková; G Schulz-Ekloff; N.I Jaeger 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 234 KB

Neutral palladium carbonyl complexes in NaX and NaY zeolites were prepared via the direct carbonylation of [Pd(NH 3 ) 4 ]2+ complexes at room temperature using the ability of noble-metal complexes to catalyze the lowtemperature water-gas shift reaction for the reduction of metal cations. The kineti