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Shifts induced by tris(dipivaloylmethanato)europium in the pmr spectra of a cetylindoles

โœ Scribed by M. Yu. Kornilov; E. D. Matveeva; V. A. Budylin; L. G. Yudin; A. N. Kost


Book ID
112329517
Publisher
Springer US
Year
1973
Tongue
English
Weight
122 KB
Volume
9
Category
Article
ISSN
0009-3122

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## Tris(dipivaloy1methanato)europium [Eu(DPM),] induced shifts of the proton resonances of pyridine and its 2-methy1, 3-methy1, 2,3-dimethyl and 2,5-dimethyl derivatives, pyridazine, pyrimidine, pyrazine, quinoline, isoquinoline, 1,6-, 1,7-and 1 &naphthyridine, cinnoline, phthalazine, quinazoline,

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Like Wahl and Peterson,' we have recently used the NMR shift reagent, tris(dipivalomethanato)europium III [Eu(dpm)JZp3 to simplify the spectra of 2-hydroxyadamantane and in addition we have also studied a variety of I-R-adamantanes(R = (CH2),CH, n= 1, 2, 3) and cyclopentanol. Wahl and Peterson have

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I J Tris(dipivalomethanato)e~opium(llI) has beem used as an NMR shift reagent to obtain simpli6ed spectra of tropine, of coordination was secondary amine > secondary alcohol > tertiary amine h ketone. . . .~ systems containing two different heteroatoms. The observed order tra of bifuictionai tropane