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Shifting the Competition between the Intramolecular Reshuffling Reaction and the Direct Oxidation Reaction during the Oxidative Folding of Kinetically Trapped Disulfide-Insecure Intermediates †

✍ Scribed by Narayan, Mahesh; Welker, Ervin; Wanjalla, Celestine; Xu, Guoqiang; Scheraga, Harold A.


Book ID
121715647
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
79 KB
Volume
42
Category
Article
ISSN
0006-2960

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## Abstract The kinetics of the reaction of __cis__‐(NO)~2~ with solid oxygen to form __iso__‐N~2~O~4~ have been studied between 13 and 29 K. The overall reaction is pseudo first order in __cis__‐(NO)~2~, and solid oxygen serves both as a reactant and the matrix. The pseudo‐first‐order rate constan