Shearing-Like Distortion in Binuclear End-to-End CuII Azido Compounds: An Ab Initio Study of the Magnetic Interactions (Eur. J. Inorg. Chem. 28/2007)

Shearing-Like Distortion in Binuclear En

Shearing-Like Distortion in Binuclear End-to-End CuII Azido Compounds: An Ab Initio Study of the Magnetic Interactions

✍ Maria Angels Carvajal; Christophe Aronica; Dominique Luneau; Vincent Robert 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 136 KB

## Abstract The direct control of magnetic interactions in Cu^II^ azido‐bridged binuclear complexes is investigated by means of explicitly correlated ab initio calculations. It is shown that in the end‐to‐end series, the shearing‐like asymmetry parameter __δ__ = __d__~long~(Cu–N) – __d__~short~(Cu–