Shear induced crystallization of poly(L-lactide) and poly(ethylene glycol) (PLLA-PEG-PLLA) copolymers with different block length
✍ Scribed by Xiao Hu; Jia-Zhuang Xu; Gan-Ji Zhong; Xiang-Lin Luo; Zhong-Ming Li
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 304 KB
- Volume
- 18
- Category
- Article
- ISSN
- 1022-9760
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## Abstract The confined crystallization behavior, melting behavior, and nonisothermal crystallization kinetics of the poly(ethylene glycol) block (PEG) in poly(L‐lactide)–poly(ethylene glycol) (PLLA–PEG) diblock copolymers were investigated with wide‐angle X‐ray diffraction and differential scanni
Poly(ethylene glycol)-poly(L-lactide) diblock and triblock copolymers were prepared by ring-opening polymerization of L-lactide with poly(ethylene glycol) methyl ether or with poly(ethylene glycol) in the presence of stannous octoate. Molecular weight, thermal properties, and crystalline structure o
## Abstract PLLA‐MPEG diblock copolymers with a controlled number‐average molar mass ranging from 7 330 to 117 610 g · mol^−1^ and an L‐lactide conversion ranging from 65.1 to 97.3% were synthesized effectively in 20 min at 100 °C by MPEG‐initiated ROP of L‐lactide under microwave irradiation. Prol