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Shape-Selective Interception by Hydrocarbons of the O2-Derived Oxidant of a Biomimetic Nonheme Iron Complex

✍ Scribed by Anusree Mukherjee; Marlène Martinho; Emile L. Bominaar; Eckard Münck; Lawrence Que Jr.

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
379 KB
Volume
121
Category
Article
ISSN
0044-8249

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✦ Synopsis

Abstract

Wählerisches Ferryl: [Fe(Tp)(BF)] (Tp=Hydrotris(3,5‐diphenylpyrazolyl)borat; BF=Benzoylformiat) liefert mit O~2~ ein Oxidationsmittel (siehe Bild; O rot, rosa, Fe gelb, N blau, C grau, H weiß), das Kohlenwasserstoffe formselektiv oxidiert. Die Ursache hierfür ist eine durch zwei Phenylgruppen des Tp‐Liganden gebildete Spalte, die abgeflachte spheroidale Substrate bevorzugt.magnified image

📜 SIMILAR VOLUMES

Shape-Selective Interception by Hydrocar
Shape-Selective Interception by Hydrocarbons of the O2-Derived Oxidant of a Biomimetic Nonheme Iron Complex
✍ Anusree Mukherjee; Marlène Martinho; Emile L. Bominaar; Eckard Münck; Lawrence Q 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 379 KB

## Abstract **Picky ferryl**: The complex [Fe(Tp)(BF)] (Tp=hydrotris(3,5‐diphenylpyrazolyl)borate; BF=benzoylformate) reacts with O~2~ to generate an oxidant (see picture; O red, pink; Fe yellow; N blue; C gray; H white) that oxidizes added hydrocarbons shape‐selectively. Discrimination derives fro