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Shape resonance in the 4d ionization of the molecular caesium halides

✍ Scribed by J.M. Benson; I. Novak; A.W. Potts

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
294 KB
Volume
140
Category
Article
ISSN
0009-2614

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✦ Synopsis

Photoelectron asymmetry parameters (8) have been measured for photoionization from the Cs+ 4d subshells in the molecular caesium halides using photons in the energy range 50-l 20 eV. A resonance is observed in the p spectrum close to threshold and is assigned to a centrifugal barrier shape resonance.

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Previous work.on photoionization threshold, I,l, determinations, for aromatics dispersed in ri,$d ghss~ at 77 K, has 'now been extended to polycrystalline hydrocarbons as solid solvents. TlMPD being wed as a solute, the i.nfIuence on I~],TMPD of the linear or globular ahape of the solvent molecule i