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Shape-memory polymer networks from sol–gel cross-linked alkoxysilane-terminated poly(ε-caprolactone)

✍ Scribed by Katia Paderni; Stefano Pandini; Simone Passera; Francesco Pilati; Maurizio Toselli; Massimo Messori

Publisher
Springer
Year
2012
Tongue
English
Weight
383 KB
Volume
47
Category
Article
ISSN
0022-2461

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## Abstract Cross‐linked poly(ε‐caprolactone) (PCL)‐based polyesterurethane (PUR) systems have been synthesized through Diels–Alder reactions by reactive extrusion. The Diels–Alder and retro‐Diels–Alder reactions proved to be useful for enhancing the molecular motion of PCL‐based systems, and there