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Sesquiterpenoids. Part V. The stereochemistry of the tricyclic derivatives of caryophyllene

✍ Scribed by Aebi, A. ;Barton, D. H. R. ;Burgstahler, A. W. ;Lindsey, A. S.


Book ID
124102486
Publisher
The Royal Society of Chemistry
Year
1954
Weight
619 KB
Category
Article
ISSN
0368-1769

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Evidences; about the stereochemistry of
✍ A.F Barrero; J.E Oltra; A BarragΓ‘n πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 276 KB

From natural 14-hydroxy-Q-epi-P-caryophyllene (11, the acyl derivatives 2 and 3 were prepared. These compounds appeared as a mixture of two conformational isomers (7/3). When 1 was oxidized with HCPBA, epoxides 7 and Q were obtained. The rigid conformation of 7 and Q allowed us to establish their sk