SERS on photographic silver halide emulsions
β Scribed by K. Kneipp; W. Jahr; G. Roewer
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 448 KB
- Volume
- 163
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Surface-enhanced Raman Scattering (SERS) investigations on a cyanine dye in photographic silver halide emulsions with various photographically relevant additives are reported. In addition to an electromagnetic enhancement due to Giver particles of suitable size and shape a chemical enhancement which is directly connected with the thiosulfate digestion of the emulsion, i.e. the formation of Ag,S, plays an important role. In photographic emulsions sensitivity centres and SERS active sites arc identical. A strong influence of the additives (stabilizers and antifogging agents) on the chemical SERS enhancement was found.
π SIMILAR VOLUMES
## Abstract Nucleation and crystal growth processes involved in the batch precipitation of photographic emulsions by the addition of silver nitrate to an aqueous solution of bromide and gelatin have been reasonably successfully modeled. Simulation predicts the known increase in average crystal size