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Sequential [3,3]Sigmatropic Rearrangement: Regioselective Synthesis of Dimedone‐Annulated Heterocycles

✍ Scribed by Samanta, S. K.; Majumdar, K. C.


Book ID
121509965
Publisher
Taylor and Francis Group
Year
2006
Tongue
English
Weight
107 KB
Volume
36
Category
Article
ISSN
0039-7911

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Regioselective synthesis of polyheterocy
✍ K. C. Majumdar; S. Muhuri 📂 Article 📅 2007 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 395 KB

## Abstract magnified image A number of tetracyclic polyhetero scaffolds have been regioselectively synthesised in 70‐75% yield from 4‐[(3‐aryloxy‐2‐propynyl)oxy]‐6‐methyl‐pyran‐2‐ones __via__ thionation of the lactone carbonyl, sequential Claisen rearrangements and pyridine hydrotribromide mediat