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Sequence-Specific Unusual (1→2)-Type Helical Turns in α/β-Hybrid Peptides

✍ Scribed by Prabhakaran, Panchami; Kale, Sangram S.; Puranik, Vedavati G.; Rajamohanan, P. R.; Chetina, Olga; Howard, Judith A. K.; Hofmann, Hans-Jörg; Sanjayan, Gangadhar J.


Book ID
121865187
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
993 KB
Volume
130
Category
Article
ISSN
0002-7863

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Conformation of di-n-propylglycine resid
✍ Raghurama P. Hegde; Subrayashastry Aravinda; Rajkishor Rai; Ramesh Kaul; Sarojin 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 882 KB

## Abstract The crystal structures of two oligopeptides containing di‐n‐propylglycine (Dpg) residues, Boc‐Gly‐Dpg‐Gly‐Leu‐OMe (**1**) and Boc‐Val‐Ala‐Leu‐Dpg‐Val‐Ala‐Leu‐Val‐Ala‐Leu‐Dpg‐Val‐Ala‐Leu‐OMe (**2**) are presented. Peptide **1** adopts a type I′β‐turn conformation with Dpg(2)–Gly(3) at th