𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Sequence congestion effects in optical selection studies of electronic relaxation

✍ Scribed by A. Nitzan; J. Jortner


Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
549 KB
Volume
13
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


We present a theoretical study of the non-radiative decnv rate of an "isolated" large molecule characterized by displaced potcnttil surface:;, which will exhibit temperature dependence due to sequence congestion effects.

* The definition (8) amounts to replacing the !orentzian distribution in eq. ( 6) by a rectangular distribution.


πŸ“œ SIMILAR VOLUMES


Study of optical relaxation of polyatomi
✍ M.N. Sapozhnikov; V.I. Alekseev πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 English βš– 529 KB

Fluorescence line narrowing and hole burnin\_g in absorption spectra have been used for 3 study electronic and vibrational relaxations and inhomogeneous distribution function for coproporphyrin Ill molecules in solid ethanol and n-octane matrices in the tempemture range from 3.2 to 26 K.

Effects of non-Debye solvent relaxation
✍ Teresa Fonseca πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 532 KB

To assess the importance of the different time scales of non-Debye solvent relaxation on the reaction kinetics of electron transfer reactions we have performed a numerical simulation study for a model system of an activated solvent-controlled electron transfer reaction in the weakly adiabatic regime