Sequence congestion effects in optical selection studies of electronic relaxation
β Scribed by A. Nitzan; J. Jortner
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 549 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
We present a theoretical study of the non-radiative decnv rate of an "isolated" large molecule characterized by displaced potcnttil surface:;, which will exhibit temperature dependence due to sequence congestion effects.
* The definition (8) amounts to replacing the !orentzian distribution in eq. ( 6) by a rectangular distribution.
π SIMILAR VOLUMES
Fluorescence line narrowing and hole burnin\_g in absorption spectra have been used for 3 study electronic and vibrational relaxations and inhomogeneous distribution function for coproporphyrin Ill molecules in solid ethanol and n-octane matrices in the tempemture range from 3.2 to 26 K.
To assess the importance of the different time scales of non-Debye solvent relaxation on the reaction kinetics of electron transfer reactions we have performed a numerical simulation study for a model system of an activated solvent-controlled electron transfer reaction in the weakly adiabatic regime