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Sequence- and Regioselectivity in the Montmorillonite-Catalyzed Synthesis of RNA

✍ Scribed by Miyakawa, Shin; Ferris, James P.

Book ID
127267763
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
77 KB
Volume
125
Category
Article
ISSN
0002-7863

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✍ Subbareddy Kanagasabapathy; Arumugam Sudalai; Brian C Benicewicz πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 66 KB

The addition of thiols and thiobenzoic acids onto olefins proceeded regioselectively in a Markovnikov manner in the presence of Montmorillonite K 10 (Mont K 10) clay as the catalyst to afford thioethers and thiocarboxylic S-esters, while high selectivity to anti-Markovnikov products was realized in