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Sequence and branching distribution of ethylene/1-butene copolymers prepared with a soluble vanadium-based Ziegler-Natta catalyst

✍ Scribed by Kuroda, Nobuyuki; Nishikitani, Yoshinori; Matsuura, Kazuo; Ikegami, Noboru

Book ID
120916927
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
770 KB
Volume
25
Category
Article
ISSN
0024-9297

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Comparison with the conventional ZieglereNatta catalyst TiCl 4 /MgCl 2 (I), the modified supported Zie-glereNatta catalysts (iso-PentylO)TiCl 3 /MgCl 2 (II) and (BzO)TiCl 3 /MgCl 2 (III) were prepared as efficient catalysts for copolymerization of ethylene with 1-octene. The complexes (II) and (III)