Synthesis of Methyl D-and L-Glycero-α-D-manno-heptofuranosides. -The preparation of the title compounds (X) and (V), resp., via two carbon atom elongation of a lyxofuranoside system [→ (V)] or one carbon atom homologation of suitably blocked α-D-mannofuranoside [→ (X)].
Septanose Carbohydrates: Synthesis and Conformational Studies of Methyl α-D-Glycero-D-idoseptanoside (I) and Methyl β-D-Glycero-D-guloseptanoside (II).
✍ Scribed by Matthew P. DeMatteo; Nicole L. Snyder; Martha Morton; Donna M. Baldisseri; Christopher M. Hadad; Mark W. Peczuh
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 12 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Five Monophosphates of Methyl L-glycero-α-D-manno-Heptopyranoside: Synthesis, Hydrolysis and Migrations. -The title compounds are prepared from suitably protected methyl α-Dmannopyranosides according to a reported protocol based on a one-carbon-atom chain elongation at C-6 via Swern oxidation
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Stereoselective Synthesis of 3'-Fluoro-and 3'-Azido-4'-methyl-2',3'-D-glycero-pentofuranoside-5-fluorouracils. -The synthesis of the title compounds is achieved via stereoselective formation of the epoxide (III) and its regioselective nucleophilic cleavage. -(RIEHOKAINEN, E.; MIKERIN, I. E.;