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Separation of xylenols by inclusion

✍ Scribed by Mino R. Caira; Luigi R. Nassimbeni; Dejana Vujovic; Fumio Toda

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 80 KB
Volume: 13
Category: Article
ISSN: 0894-3230
DOI: 10.1002/(sici)1099-1395(200001)13:1<75::aid-poc193>3.0.co;2-a

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✦ Synopsis

The host 1,1-bis(4-hydroxyphenyl)cyclohexane, H, forms 1:1 inclusion compounds with 2,3-xylenol, H Á 23X, and with 3,5-xylenol, H Á 35X. Competition experiments were conducted to determine the host selectivity toward three xylenol isomers, 2,3-, 3,5-and 2,6-xylenol. The structure of the solid formed between H and a mixture of 23X and 35X was elucidated.

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