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Separation of synthesized enantiomers and diastereomers of thiino-[4,3-b]pyrrole-2,3-dione derivatives and 2H-thiopyrans by capillary electrophoresis

✍ Scribed by Thorsten Blitzke; Horst Wilde; Dr. Carla Vogt


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
588 KB
Volume
18
Category
Article
ISSN
0173-0835

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Starting from tetrahydrothiopyran-4-one (4d) a rational NMR spectra, redox behavior, and crystal structure (H 4 -3a and 3a). The very low solubility of 3a and 3b prevented eight-step synthesis of 3a has been developed with 25 % overall yield. This route passes H 4 -3a and H 2 -3a which are further r