Separation of methane—nitrogen mixtures by pressure swing adsorption using a carbon molecular sieve
✍ Scribed by A.I. Fatehi; K.F. Loughlin; M.M. Hassan
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 535 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0950-4214
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✦ Synopsis
A 60% 40% and a 92%-8% methane nitrogen mixture were separated in a two-bed pressure swing adsorption (PSA) unit using a carbon molecular sieve (CMS) adsorbent.
The CMS adsorbent used in this separation is a dual resistance type comprising a barrier resistance on the crystal surface and diffusion resistance in the crystal interior. This dual resistance is modelled using the linear driving force (LDF) PSA model. The parameter D of the LDF model, which relates the theoretical and experimental results, was found to be significantly different from that for conventional diffusion-controlled processes. This difference is attributed to the presence of a barrier resistance in the CMS.
📜 SIMILAR VOLUMES
A simplitied dynamic model for a PSA air separation process is developed based on linearized mass transfer rate expressions and binary Langmuir equilibrium. Constant pressure is assumed during adsorption and desorption steps but the variation in flow rate through the column due to adsorption is aeeo
Pressure swing adsorption (PSA) processes based on carbon molecular sieves have been known for more than twenty years. The most impo~ant industrial PSA process, the nitrogen PSA process, has been developed during the last ten years into a highly efficient technique for producing nitrogen on site. Ni