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Separation of cistrans-cyclohexanecarboxylates by enzymatic hydrolysis: Preference for diequatorial isomers

✍ Scribed by Kurt Königsberger; Hector Luna; Kapa Prasad; Oljan Repic; Thomas J. Blacklock

Book ID: 104255911
Publisher: Elsevier Science
Year: 1996
Tongue: French
Weight: 195 KB
Volume: 37
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(96)02120-x

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✦ Synopsis

4-Substituted cis/trans-cyclohexanecarboxylates have been separated into the isomers by enzymatic hydrolysis with lipase from Candida rugosa with very good selectivity. The enzyme preferentially recognizes diequatorial conformations.

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