A novel procedure for analysing chiral compounds is described in which a capillary electrophoresis/partial Ðlling technique was coupled on-line to micro-electrospray mass spectrometry. Enantiomers of bupivacaine and ropivacaine were separated using methyl-b-cyclodextrin, a non-volatile bu †er additi
✦ LIBER ✦
Separation and Identification of Basic Dendrimers Using Capillary Electrophoresis On-line Coupled to a Sector Mass Spectrometer
✍ Scribed by Detlef Stöckigt; Gunther Lohmer; Detlev Belder
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 460 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0951-4198
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A novel microelectrospray interface for the on-line coupling of capillary-zone electrophoresis (CZE) and mass spectrometry is described. The outlet of the fused-silica CZE capillary is tapered and serves as the microspray tip. The spray does not contain a sheath flow nor does the capillary tip conta