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Sensitized photooxidation of the dimer of spiro[2,4]hepta-4,6-diene: A novel oxidative fragmentation of the cyclopropyl group

✍ Scribed by Hitoshi Takeshita; Toshihide Hatsui; Hiroshi Kanamori

Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 208 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)96031-9

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✦ Synopsis

In our previous studies on the reaction of singlet oxygen with l-5) vinylcyclopropaner, we have observed, 1,2,4) for the first time, the C=C bond cleavage of an alicyclic olefins bearing no heteroatom, and have shown that this should directly be related with the intermediate, d i o xe t a n e, by the reaction in deuteriomethanol 3)

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