✦ LIBER ✦

Sensitized biphotonic radical-anion formation of solute—solvent electron donor—acceptor complex

✍ Scribed by Katsumi Kimura; Yohji Achiba

Book ID: 103021480
Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 331 KB
Volume: 46
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80658-1

No coin nor oath required. For personal study only.

✦ Synopsis

A solution of 1,2.4,5-tetraeyanobenzene (TCNB) in 2-methgltetrahydrofuran (MTHF), in which a solute-s.~,lvent electron donor-acceptor (EDA) complex is formed, has been photoirradiated bY 350--400 am light at 77 K so as ,o e~eiLe only benzophenone. The intensity dependence of the exciting UV light on the photoinduced radical-anion formatior~ of TCNB has been studied by means o¢ optical absorption, suggesting a sensitized biphotonic ionic dissociation of the l:].lA complex.

📜 SIMILAR VOLUMES

Photoinduced radical-anion formation fro

Photoinduced radical-anion formation from a solute-solvent electron-donor-acceptor complex. Enhancement of radical-anion formation by a positive-charge scavenger in rigid glass at 77 K

✍ Yohji Achiba; Katsumi Kimura 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 352 KB

Formation by fast atom bombardment of mo

Formation by fast atom bombardment of molecular radical cations by electron donor–acceptor complexes from tosylated amino acid esters

✍ Constantions Athanassopoulos; Dionissios Papaioannou; Anna Napoli; Carlo Sicilia 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 549 KB

## Abstract __N__‐Alkyl‐__N__‐tosyl amino acid esters were ionized by fast atom bombardment (FAB) in a nitrobenzyl alcohol matrix through oxidative processes leading to molecular radical cations (M^+·^). The addition to the matrix of Cu^11^ salts induces the ionization through proton attachment whe

Study of the formation and photochemistr

Study of the formation and photochemistry of an electron donor—acceptor (EDA) complex between benzaldehyde and methylviologen in solution

✍ M. Hamity; R.H. Lema 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 908 KB

Photo-induced generation of radicals fro

Photo-induced generation of radicals from m-dinitrobenzene adsorbed on γ-Al2O3: Direct evidence for the formation of electron donor-acceptor (EDA) complexes with participation of solvent molecules

✍ Konovalova, T. A. ;Volodin, A. M. 📂 Article 📅 1993 🏛 Springer 🌐 English ⚖ 197 KB

Investigation of electron donor–acceptor

Investigation of electron donor–acceptor complex formation between morpholine and 2,4,6-trimorpholino-1,3,5-triazin with iodine in two solvents with soft-modeling approaches

✍ Tayyebeh Madrakian; Masoumeh Mohammadnejad; Faezeh Hojati 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 460 KB

Charge transfer spectra of organometalli

Charge transfer spectra of organometallic complexes—III. Energy contributions to the formation of a donor—acceptor complex and to the electron transfer in the interaction between trialkyltin iodides and iodine in carbon tetrachloride solutions

✍ S. Hoste; G.G. Herman; W. Lippens; L. Verdonck; G. van der Kelen 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 684 KB

The enthalpies of formation for charge transfer complexes of the type [R&1.1,] (R = CH3, C2F5, n-C3H,, n-&H,) have been measured by calorimetry. The data are analysed using Mulliken's resonance structure theory, to produce the different energy contributions to the formation ofand the charge transfer