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Semiquinone-quinone redox species involving bis(bipyridine)ruthenium(II): resonance Raman spectra

✍ Scribed by Stufkens, D. J.; Snoeck, T. L.; Lever, A. B. P.


Book ID
124162787
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
591 KB
Volume
27
Category
Article
ISSN
0020-1669

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## Abstract The existence of two independent chromophores in [Ru(bipy)~2~(H~2~V)]^+^, where H~2~V^βˆ’^ = violurate anion and bipy = 2,2β€²bipyridine, was demonstrated by comparing its resonance Raman spectra with those displayed by the [Ru(H~2~V)~3~]^βˆ’^ analogue. In the former, the electronic band at 4