Semidiones. III. Radical Ions Derived from Ninhydrin and Alloxan 1
✍ Scribed by Russell, Glen A.; Young, Maria C.
- Book ID
- 120966959
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 873 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The 1,1,2,2‐bis(1,3‐diketo‐2,2‐bindanylidene)ethane radical anion (**13**) and 1,1,4,4‐bis (1,3‐diketo‐2,2‐binanylidene)butene‐2 radical anion (**14**)We employ herein nomenclature wherein the term ‘radical anion’ means the gain of one electron of the named substrate. representing 1,6‐
Radical anions and cations have been prepared by the reduction of the title compounds or their diprotonated derivatives. The same radical ions have been observed by oxidation of the dihydro derivatives. Electron spin resonance hyperfine splitting constants have been assigned on the basis of Hiickel