Semiclassical wavepacket construction of quantum resonance states from classical resonant orbits for the F + H2 reaction

✍ Scribed by C. Clay Marston; Robert C. Brown; Robert E. Wyatt

• Publisher: Elsevier Science
• Year: 1985
• Tongue: English
• Weight: 684 KB
• Volume: 122
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(85)80564-9

✦ Synopsis

The semlclasslcal Inlerpretarlon of reactive resonances as dynamvzally confined orbl[s IS extended for the F+ Hz reaction by construction of resonant-stale waveruncllons aardrng LO a rime-dependenl formahsm Tar GaussIan u.avcpacket dynamics The partruonmg of nodal curves belween entrance and exli channels ror Ihe colhnear resonances agrees with adiabatic theory and nodal surfaces for the 3D probablhly densely dlstrlbutlon quahtallvely agree with quanta1 calculations * Supported in part by research grants from the National Science Foundahon and Ihe Robert A Welch Foundarlon * Seeref. [2] ofref [l]. ** See refs. [5-91 of ref. [ 11. * The potential surface (Muckerman V [12]) used in refs [1,8,9] will also be used hme.