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Semiclassical formulation of multiphoton unimolecular dissociation

✍ Scribed by Prescila García-Fernández; P.F. González-Díaz

Book ID
103317106
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
528 KB
Volume
57
Category
Article
ISSN
0030-4018

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📜 SIMILAR VOLUMES

Unimolecular dissociation rates by a sem
Unimolecular dissociation rates by a semiclassical analysis of quantum resonance lifetimes
✍ Vincenzo Aquilanti; Simonetta Cavalli; Gaia Grossi 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 542 KB

A semiclassical analysis of quantum-mechanical resonance lifetimes provides a framework for describing unimolecular dissociation rates near or below the adiabatic thresholds associated with saddles on potential energy surfaces. A formula which can be used when only one channel is effectively open is