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Semiclassical calculation of Franck-Condon intensities for reactive systems

✍ Scribed by Bruce W. Spath; William H. Miller

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
476 KB
Volume
262
Category
Article
ISSN
0009-2614

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✦ Synopsis

A Filinov transformation of the initial value representation of the semiclassical propagator has been used to obtain Franck-Condon intensities for a model of the photodetachment of H~-~ H + H2 + e-. Resonance peak widths and heights are obtained which are in good agreement with quantum results.

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Exact semiclassical calculation of eigen
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An exact method utilizing integration along invariant curves on PoincarΓ© surfaces of section is described for semiclassical calculation of eigenvalues. The surfaces of section (SOS) method has been shown to be easily applied to two-and three-dimensional quasiperiodic systems with degenerate or nonde