Self-similar approximations for thermodynamic potentials
β Scribed by V.I. Yukalov; E.P. Yukalova
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 920 KB
- Volume
- 198
- Category
- Article
- ISSN
- 0378-4371
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β¦ Synopsis
The method of self-similar approximations is extended here to the problem of calculating thermodynamic potentials in statistical mechanics.
To formulate an optimal scheme of the method, we compare its different variants connected with different definitions of governing functions and damping parameters.
Stability conditions are analyzed. All conclusions are made apparent by calculating the free energy of a zero-dimensional 'p' model. The optimal variant of the method is shown to be stable providing a good accuracy in the whole range of a coupling parameter, from zero up to infinity.
π SIMILAR VOLUMES
A novel method of summation for power series is developed. The method is based on the self-similar approximation theory. The trick employed is in transforming, ΓΏrst, a series expansion into a product expansion and in applying the self-similar renormalization to the latter rather to the former. This
## Abstract **Summary:** An explicit expression is derived for the distribution function of endβtoβend vectors for a flexible selfβavoiding chain. Based on this relation, analytical formulas are developed for the free and internal energies of a chain with excludedβvolume interactions. Forceβstretch