An expenmental techmque has been developed to differentlate between umform polsonmg and pore-mouth polsomng of porous catalysts for a first-order reactlon Data for the hydrogenolysls of cyclopropane on an alumma-supported platmum catalyst dunng polsomng mdlcated that the polsonmg mechamsm was betwee
Self-poisoning reactions in the single-pellet catalytic reactor
β Scribed by N.A. Dougharty
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 468 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0009-2509
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β¦ Synopsis
The single-pellet reactor, in which in effect the reactant concentration at the center-plane of a porous catalyst pellet of slab geometry can be measured, can provide information on the concentration dependence of self-poisoning rates of heterogeneously catalyzed reactions. The method is illustrated by application to data for the hydrogenation of cyclopropane over Pt/AI,O,.
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