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Self-Organized Lateral Patterning of a Rare Earth Complex and Stearic Acid in Langmuir Films

✍ Scribed by Ren-Jie Zhang; Peter Krüger; Bernd Kohlstrunk; Mathias Lösche

Book ID: 101355925
Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 167 KB
Volume: 2
Category: Article
ISSN: 1439-4235
DOI: 10.1002/1439-7641(20010716)2:7<452::aid-cphc452>3.0.co;2-j

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✦ Synopsis

Metal supercomplexes form on compression of a film of the individual complexes mixed with a fatty acid: A suite of techniques--Langmuir film balance, and optical and scanning force microscopy--show the transformation of [Eu(tta)3 (phen)] into a thin film of strongly luminescent tetrameric supercomplexes. When the area per molecule is low, a phase-separated meshwork structure forms. The cartoon shows the surface arrangement, in which the supercomplexes sit on a layer of the single europium complexes and corralled by a fatty acid.

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