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Self-induced short chain branching in homopolymers and 1-hexene copolymers of ethylene produced with amido functionalized ansa half-sandwich complexes as catalysts

โœ Scribed by Helmut G. Alt; Alexander Reb; M. Bruce Welch; Antoni Jurkiewicz


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
96 KB
Volume
100
Category
Article
ISSN
0021-8995

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Full Paper: Copolymerization of ethylene and 1-hexene was carried out with different catalysts: homogeneous Et[Ind] 2 ZrCl 2 , Cp 2 HfCl 2 and [(C 5 Me 4 )SiMe 2 N(tert-Bu)]TiCl 2 , the corresponding in-situ supported metallocenes, and combined in-situ supported metallocene catalysts (mixtures of Et