✦ LIBER ✦
Self-ignition of small-ring hydrocarbons behind reflected shock waves
✍ Scribed by V.G. Slutsky; O.D. Kazakov; E.S. Severin; E.V. Bespalov; S.A. Tsyganov
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 344 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0010-2180
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✦ Synopsis
Self-ignition of stoichiometric airlike argon mixtures of monocyclic and bicyclic small-ring hydrocarbons was investigated behind reflected shock waves at 1200-1600 K and 0.6 + 0.1 MPa. The reactivity of small-ring hydrocarbons has been found to be determined by the properties of their thermal decomposition products. New high-temperature decomposition channels for spiropentane, methylenecyclobutane, and methylenecyclopropane have been discovered.